ENGAGE9130POEHM7280
对比传统的聚合物材料,具有更好的加工成型性能,成型时不需加任何塑化剂;在汽车工业、医用、抗冲击改性剂及包装领域有着***的应用。POE美国陶氏弹性体塑料其他型号如下:品名型号TPO(POE)ENGAGE8440GTPO(POE)ENGAGE8150TPO(POE)ENGAGE8137TPO(POE)ENGAGE8130TPO(POE)ENGAGE8180TPO(POE)ENGAGE8450TPO(POE)ENGAGE8450GTPO(POE)ENGAGE8452ELTPO(POE)ENGAGE8452TPO(POE)ENGAGE8457DATPO(POE)ENGAGE8480TPO(POE)ENGAGE8540TPO(POE)ENGAGE8540GTPO(POE)ENGAGE8842TPO(POE)ENGAGEHM7280TPO(POE)ENGAGEHM7289TPO(POE)ENGAGEHM7387TPO(POE)ENGAGEHM7487TPO(POE)ENGAGEXLT8677TPO(POE)VERSIFY2300TPO(POE)VERSIFY3300TPO(POE)VERSIFY3401TPO(POE)(聚烯烃弹性体#聚乙烯辛烯共弹性体)/8200/美国杜邦用途:其它重要参数:熔体流动速率:5g/10min密度:g/cm3拉伸强度:MPa断裂伸长率:1000%硬度:75生产厂商:美国杜邦公司(聚烯烃弹性体#聚乙烯辛烯共弹性体)/8100/美国杜邦用途:其它重要参数:熔体流动速率:1g/10min密度:g/cm3拉伸强度:MPa断裂伸长率:750%硬度:75生产厂商:美国杜邦公司。陶氏聚烯烃弹性体POE可以用于制造各种家居用品、办公用品等。ENGAGE9130POEHM7280
6-二乙基苯胺)-2-(2,6-二(二苯甲基)-3,4-二氟苯胺)苊]合溴化镍(ii)[配合物c2],其中r1为乙基,r2为氢,x为溴。室温下,将(dme)nibr2()和实施例3所制备的1-(2,6-二乙基苯胺)-2-(2,6-二(二苯甲基)-3,4-二氟苯胺)苊()混合溶于二氯甲烷中,在氮气保护下搅拌16h,减压除去二氯甲烷后加入**有棕色固体析出,过滤,**洗涤,烘干,得到棕色固体。产率:73%.结构确证数据如下:ft-ir(cm-1):2969(w),1644(νc=n,m),1620(νc=n,w),1579(m),1474(s),1447(m),1415(m),1322(m),1292(m),1224(w),1183(m),1074(m),1000(m),960(w),864(m),826(m),768(s),697(vs).元素分析:c54h42br2f2n2ni()理论值:c,;h,;n,;h,;n,.实施例9本实施例中,制备式(i)所示的α-二亚胺镍配合物:[1-(2,6-二异丙基苯胺)-2-(2,6-二(二苯甲基)-3,4-二氟苯胺)苊]合溴化镍(ii)[配合物c3],其中r1为异丙基,r2为氢,x为溴。室温下,将(dme)nibr2()和实施例4所制备的1-(2,6-二异丙基苯胺)-2-(2,6-二(二苯甲基)-3,4-二氟苯胺)苊()混合溶于二氯甲烷中,在氮气保护下搅拌16h,减压除去二氯甲烷后加入**有棕色固体析出,过滤,**洗涤,烘干,得到棕色固体。产率:65%.结构确证数据如下:ft-ir(cm-1):2968(s),2901(w)。ENGAGE8180POEHM7487POE材料可以通过热成型、压缩成型等工艺制造成各种形状的制品。
mmao)作为助催化剂,在加压环境下进行乙烯聚合反应:过程基本同实施例13(e),区别在于:主催化剂为式(ii-5)所述α-二亚胺镍配合物。聚合活性:×106g·mol-1(ni)·h-1,聚合物tm=℃,mw=×105g·mol-1,pdi=。实施例18本实施例中,采用式(ii-1)所示α-二亚胺镍配合物作为主催化剂,氯化二甲基铝(me2alcl)作为助催化剂,在加压环境下进行乙烯聚合反应:(a)在乙烯气氛下,将20ml甲苯、30ml的主催化剂(2μmol)的甲苯溶液、()、50ml甲苯依次加入到250ml不锈钢高压釜中。此时al/ni=500:1。机械搅拌开始,保持400转/分,当聚合温度达到30℃时,往反应釜中充入乙烯,聚合反应开始。在30℃下保持10atm的乙烯压力,搅拌30min。用5%盐酸酸化的乙醇溶液中和反应液,得到聚合物沉淀,用乙醇洗数次,真空烘干至恒重,称重。聚合活性:×106g·mol-1(ni)·h-1,聚合物tm=℃。(tm为聚合物的熔融温度,通过dsc测试所得),聚合物分子量mw=×105g·mol-1,pdi=(mw为聚合物的质均分子量,通过升温gpc测试所得)。(b)基本同(a),区别在于:助催化剂用量为(),使al/ni=200:1。聚合活性:×106g·mol-1(ni)·h-1,聚合物tm=℃,mw=×105g·mol-1,pdi=。(c)基本同(a)。
POE美国陶氏ENGAGE塑料简介:POE分两种,一种是乙烯和丁烯的高聚物,另一种是乙烯和辛烯的高聚物。POE塑料是采用茂金属催化剂的乙烯和辛烯实现原位聚合的热塑性弹性体,其特点是:(1)辛烯的柔软链卷曲结构和结晶的乙烯链作为物理交联点,使它既有优异的韧性又有良好的加工性。(2)POE塑料分子结构中没有不饱和双键,具有优良的耐老化性能。(3)POE塑料分子量分布�**,具有较好的流动性,与聚烯烃相容性好。(4)良好的流动性可改善填料的分散效果,同时也可提高制品的熔接痕强度。随着POE塑料含量的增加,体系的冲击强度和断裂伸长率有很大的提高。可见,POE塑料对PP有优良的增韧作用,与PP、活性碳酸钙有较好的相容性。这是因为POE塑料的分子量分布�**,分子结构中侧辛基长于侧乙基,在分子结构中可形成联结点,在各成分之间起到联结、缓冲作用,使体系在受到冲击时起分散、缓冲冲击能的作用,减少银纹因受力发展成裂纹的机会,从而提高了体系的冲击强度。当体系受到张力时,由于这些联结点所形成的网络状结构可以发生较大的形变,所以,体系的断裂伸长率有***的增加,当POE塑料的含量增加时,体系的拉伸强度、弯曲强度和弯曲模量均有所下降。陶氏弹性体可以被用于制造橡胶弹簧。
POE)ENGAGE8207TheDowChemicalCompanyTPO(POE)ENGAGE8400TheDowChemicalCompanyTPO(POE)ENGAGE8401TheDowChemicalCompanyTPO(POE)ENGAGE8402TheDowChemicalCompanyTPO(POE)ENGAGE8407TheDowChemicalCompanyTPO(POE)ENGAGE8411TheDowChemicalCompanyTPO(POE)ENGAGE8440TheDowChemicalCompanyTPO(POE)ENGAGE8440GTheDowChemicalCompanyTPO(POE)ENGAGE8450TheDowChemicalCompanyTPO(POE)ENGAGE8450GTheDowChemicalCompanyTPO(POE)ENGAGE8452ELTheDowChemicalCompanyTPO(POE)ENGAGE8452TheDowChemicalCompanyTPO(POE)ENGAGE8457DATheDowChemicalCompanyTPO(POE)ENGAGE8480TheDowChemicalCompanyTPO(POE)ENGAGE8540TheDowChemicalCompanyTPO(POE)ENGAGE8540GTheDowChemicalCompanyTPO(POE)ENGAGE8842TheDowChemicalCompanyTPO(POE)ENGAGE?HM7280TheDowChemicalCompanyTPO(POE)ENGAGEHM7289TheDowChemicalCompanyTPO(POE)ENGAGEHM7387TheDowChemicalCompanyTPO(POE)ENGAGEHM7487TheDowChemicalCompanyTPO(POE)ENGAGEXLT8677TheDowChemicalCompanyTPO。陶氏弹性体可以被用于制造橡胶防震垫。陶氏ENGAGE8180POEHM7280
陶氏聚烯烃弹性体POE可以用于制造各种包装材料、保护材料等。ENGAGE9130POEHM7280
POE)ENGAGE7367陶氏塑料TPO(POE)ENGAGE7387EL陶氏塑料TPO(POE)ENGAGE7447EL陶氏塑料TPO(POE)ENGAGE7447ElastomerPA陶氏塑料TPO(POE)ENGAGE7447陶氏塑料TPO(POE)ENGAGE7457陶氏塑料TPO(POE)ENGAGE7467陶氏塑料TPO(POE)ENGAGE8003EL陶氏塑料TPO(POE)ENGAGE8003陶氏塑料TPO(POE)ENGAGE8100陶氏塑料TPO(POE)ENGAGE8107陶氏塑料TPO(POE)ENGAGE8130陶氏塑料TPO(POE)ENGAGE8137PA陶氏塑料TPO(POE)ENGAGE8137陶氏塑料TPO(POE)ENGAGE8150陶氏塑料TPO(POE)ENGAGE8157陶氏塑料TPO(POE)ENGAGE8180陶氏塑料TPO(POE)ENGAGE8187PA陶氏塑料TPO(POE)ENGAGE8200陶氏塑料TPO(POE)ENGAGE8207陶氏塑料TPO(POE)ENGAGE8400陶氏塑料TPO(POE)ENGAGE8401陶氏塑料TPO(POE)ENGAGE8402陶氏塑料TPO(POE)ENGAGE8407陶氏塑料TPO(POE)ENGAGE8411陶氏塑料TPO(POE)ENGAGE8440陶氏塑料TPO(POE)ENGAGE8440G陶氏塑料TPO(POE)ENGAGE8450陶氏塑料TPO(POE)ENGAGE8450G陶氏塑料TPO(POE)ENGAGE8452EL陶氏塑料TPO(POE)ENGAGE8452陶氏塑料TPO(POE)ENGAGE8457DA陶氏塑料TPO(POE)ENGAGE8480陶氏塑料TPO(POE)ENGAGE8480KHealth陶氏塑料TPO(POE)ENGAGE8540陶氏塑料TPO(POE)ENGAGE8540G陶氏塑料TPO(POE)ENGAGE8540R陶氏塑料TPO。ENGAGE9130POEHM7280
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